Dr Lynne Wallace

+61 2 6268 8230
+61 2 6268 8017

LOCATION

Room 213 PEMS North (Bldg 22) School of Physical, Environmental and Mathematical Sciences, UNSW Canberra, Australian Defence Force Academy, PO Box 7916, Canberra BC ACT 2610, AUSTRALIA

  • ABOUT
  • PUBLICATIONS

Lynne completed her PhD at the Australian National University, after moving to Australia from Scotland.  After several postdoctoral positions (University of North Carolina at Charlotte, Australian National University and University of Strathclyde) she took up a lectureship at UNSW Canberra in 1999. 

 She currently teaches course contributions at all levels of the BSc Chemistry program, and is the Chemistry 1 laboratory coordinator.

Her main research interests include: synthesis and study of redox-active and luminescent transition metal complexes; applications of such complexes in sensor systems, light-activated molecular devices, supramolecular assemblies and therapeutic approaches; electrosynthesis of green energetic materials.

Book Chapters

Wallace L, 2014, 'Electrochemical Methods for Synthesis of Energetic Materials and Remediation of Waste Water', in Brinck T (ed.), Green Energetic Materials, Wiley, pp. 259 - 279, http://dx.doi.org/10.1002/9781118676448.ch10

Journal articles

Alrawashdeh LR; Cronin MP; Day AI; Wallace L; Woodward CE, 2018, 'Modelling the luminescence of iridium cyclometalated complexes encapsulated in cucurbituril', Analyst, vol. 143, pp. - - -, http://dx.doi.org/10.1039/C7AN01632H

Wu W; Cronin MP; Wallace L; Day AI, 2018, 'An Exploration of Induced Supramolecular Chirality Through Association of Chiral Ammonium Ions and Tartrates with the Achiral Host Cucurbit[7]uril', Israel Journal of Chemistry, vol. 58, pp. 479 - 486, http://dx.doi.org/10.1002/ijch.201700112

Konda SK; Maliki R; McGrath S; Parker BS; Robinson T; Spurling A; Cheong A; Lock P; Pigram PJ; Phillips DR; Wallace L; Day AI; Collins JG; Cutts SM, 2017, 'Encapsulation of Mitoxantrone within Cucurbit[8]uril Decreases Toxicity and Enhances Survival in a Mouse Model of Cancer', ACS Medicinal Chemistry Letters, vol. 8, pp. 538 - 542, http://dx.doi.org/10.1021/acsmedchemlett.7b00090

Al Rawashdeh L; Cronin MP; Woodward CE; Day AI; Wallace L, 2016, 'Iridium Cyclometalated Complexes in Host–Guest Chemistry: A Strategy for Maximizing Quantum Yield in Aqueous Media', Inorganic Chemistry, vol. 55, pp. 6759 - 6769, http://dx.doi.org/10.1021/acs.inorgchem.6b01037

Pandrala M; Sundaraneedi MK; Ammit AJ; Woodward CE; Wallace L; Keene FR; Collins G, 2015, 'Differential Anticancer Activities of the Geometric Isomers of Dinuclear Iridium(III) Complexes', European Journal of Inorganic Chemistry, vol. 2015, pp. 5694 - 5701, http://dx.doi.org/10.1002/ejic.201501069

Bali MS; Armitt D; Wallace L; Day AI, 2015, 'Rapid degradation of cyclic peroxides by titanium and antimony chlorides', Dalton Transactions, vol. 44, pp. 6775 - 6783, http://dx.doi.org/10.1039/c5dt00200a

Gorle AK; Feterl M; Warner JM; Wallace L; Keene FR; Collins JG, 2014, 'Tri- and tetra-nuclear polypyridyl ruthenium( ) complexes as antimicrobial agents', Dalton Trans., vol. 43, pp. 16713 - 16725, http://dx.doi.org/10.1039/C4DT02139H

Gorle AK; Ammit AJ; Wallace L; Keene FR; Collins JG, 2014, 'Multinuclear ruthenium( ) complexes as anticancer agents', New Journal of Chemistry, vol. 38, pp. 4049 - 4059, http://dx.doi.org/10.1039/C4NJ00545G

Bali MS; Wallace L; Day AI; Armitt D, 2014, 'Cyclic pentanone peroxide: Sensitiveness and suitability as a model for triacetone triperoxide', Journal of Forensic Sciences, vol. 59, pp. 936 - 942, http://dx.doi.org/10.1111/1556-4029.12439

Alrawashdeh LR; Day AI; Wallace L, 2013, 'Strong enhancement of luminescence from an iridium polypyridyl complex via encapsulation in cucurbituril', Dalton Transactions, vol. 42, pp. 16478 - 16481, http://dx.doi.org/10.1039/c3dt51836a

Pandrala M; Li F; Wallace L; Steel PJ; Moore B; Autschbach J; Collins JG; Keene FR, 2013, 'Iridium(iii) Complexes Containing 1,10-Phenanthroline and Derivatives: Synthetic, Stereochemical, and Structural Studies, and their Antimicrobial Activity', Australian Journal of Chemistry, vol. 66, pp. 1065 - 1073, http://dx.doi.org/10.1071/CH13264

Pandrala M; Li F; Feterl M; Mulyana Y; Warner JM; Wallace L; Keene FR; Collins JG, 2013, 'Chlorido-containing ruthenium(ii) and iridium(iii) complexes as antimicrobial agents', Journal of the Royal Chemical Society, Dalton Transactions, vol. 42, pp. 4686 - 4694, http://dx.doi.org/10.1039/c3dt32775b

Underwood C; Wall C; Provatas A; Wallace L, 2012, 'New high nitrogen compounds azoxytriazolone (AZTO) and azotriazolone (azoTO) as insensitive energetic materials', New Journal of Chemistry, vol. 36, pp. 2613 - 2617, http://dx.doi.org/10.1039/c2nj40800g

Wallace L; Underwood C; Day AI; Buck DP, 2011, 'Electrochemical reduction of nitrotriazoles in aqueous media as an approach to the synthesis of new green energetic materials', New Journal of Chemistry, vol. 35, pp. 2894 - 2901, http://dx.doi.org/10.1039/C1NJ20770A

Pisani M; Zhao Y; Wallace L; Woodward CE; Keene FR; Day AI; Collins JG, 2010, 'Cucurbit[10]uril binding of dinuclear platinum(II) and ruthenium(II) complexes: association/dissociation rates from seconds to hours', Journal of the Royal Chemical Society, Dalton Transactions, vol. 39, pp. 2078 - 2086, http://dx.doi.org/10.1039/b921172a

Wallace L; Cronin MP; Day AI; Buck DP, 2009, 'Electrochemical Method Applicable to Treatment of Wastewater from Nitrotriazolone Production', Environmental Science and Technology, vol. 43, pp. 1993 - 1998, http://dx.doi.org/10.1021/es8028878

Cronin MP; Day AI; Wallace L, 2007, 'Electrochemical remediation produces a new high-nitrogen compound from NTO wastewaters', Journal of Hazardous Materials, vol. 149, pp. 527 - 531, http://dx.doi.org/10.1016/j.jhazmat.2007.08.007

Riesen HA; Wallace L, 2003, 'Non-photochemical spectral hole-burning mediated by water molecules in interligand pockets of [Cr(terpy)2]3+', Physical Chemistry Communications (PhysChemComm), vol. 6, pp. 9 - 11, http://dx.doi.org/10.1039/b209460f

Riesen HA; Wallace L; Krausz E, 2000, 'Probing the electronic structures of coordination compounds by transient spectral hole-burning. Applications to specifically deuterated [Ru(bpy)] complexes', Inorganic Chemistry, vol. 39, pp. 5044 - 5052, http://dx.doi.org/10.1021/ic0005386

Wallace L; Riesen H; Krausz E, 1997, 'Dynamical Processes in the Lowest-Excited Triplet Metal-to-Ligand Charge Transfer States of Ruthenium and Osmium Diimine Complexes in Crystals', International Reviews In Physical Chemistry, vol. 16, pp. 291 - 359

Riesen H; Wallace L; Krausz E, 1997, 'Dynamical processes in the lowest-excited triplet metal-to-ligand charge transfer states of ruthenium and osmium diimine complexes in crystals', International Reviews in Physical Chemistry, vol. 16, pp. 291 - 359, http://dx.doi.org/10.1080/014423597230217

Riesen H; Wallace L; Krausz E, 1996, 'Intramolecular mini-excitons in the series [Os(bpy)3-x(bpy-d8)x]2+ (x = 0-3) in [Zn(bpy)3](ClO4)2 and [Ru(bpy)3](ClO4)2 (bpy = 2,2′-bipyridine)', Molecular Physics, vol. 87, pp. 1299 - 1316, http://dx.doi.org/10.1080/00268979650026820

Riesen H; Wallace L; Krausz E, 1996, 'Localized 3MLCT transitions in [Ru(bpy)3-x(bpy-6,6′-d2)x]2+ (x = 0-3, bpy = 2,2′-bipyridine). Probing minimally perturbed chromophores', Journal of Physical Chemistry, vol. 100, pp. 17138 - 17144

Riesen H; Wallace L; Krausz E, 1996, 'Vibrational sidelines in the localized3MLCT emission of [Ru(bpy)2(bpz)]2+ in [Zn(bpy)3](ClO4)2 (bpy = 2,2′-Bipyridine, bpz = 2,2′-Bipyrazine)', Journal of Physical Chemistry, vol. 100, pp. 4390 - 4394

Riesen H; Wallace L; Krausz E, 1996, 'Localized 3MLCT Excitations of [Ru(bpy)3-x,(bpy-6,6′-d2)x]2+ (x = 0-3) in [Zn(bpy)3](ClO4)2 (bpy = 2,2′-Bipyridine)', Inorganic Chemistry, vol. 35, pp. 6908 - 6909

Wallace L; Jackman DC; Paul Rillema D; Merkert JW, 1995, 'Temperature Dependent Emission Properties of Rhenium(I) Tricarbonyl Complexes Containing Alkyl- and Aryl-Substituted Phenanthrolines as Ligands', Inorganic Chemistry, vol. 34, pp. 5210 - 5214, http://dx.doi.org/10.1021/ic00125a020

Wallace L; Woods C; Rillema DP, 1995, 'Structure and Luminescence Properties of [Re(4,7-dimethyl-l,10-phenanthroline)(CO)3py]+ in a Solid Matrix', Inorganic Chemistry, vol. 34, pp. 2875 - 2882, http://dx.doi.org/10.1021/ic00115a014

Riesen H; Wallace L; Krausz E, 1995, 'Vibrational sidelines in the localized 3MLCT luminescence of [Ru(bpy)3-x(L)x]2+ (x=0 to 3, L = 3,3′-bipyridazine, bpy-d8) in the C2/c [Zn(bpy)3](ClO4)2 lattice', Chemical Physics, vol. 198, pp. 269 - 280, http://dx.doi.org/10.1016/0301-0104(95)00190-Y

Riesen H; Wallace L; Krausz E, 1995, 'Site-selective and Stark spectroscopy of the series [Os(2,2′- bipyridine)3-x(2,2′-bipyridine-d8)x] 2+ (x=0-3) in single-crystal [Ru(2,2′-bipyridine) 3](PF6)2. Localization of an intramolecular triplet metal-to-ligand charge transfer exciton by partial deuteration', The Journal of Chemical Physics, vol. 102, pp. 4823 - 4831, http://dx.doi.org/10.1063/1.469530

Riesen H; Wallace L; Krausz E, 1995, 'Deuteration effects in the lowest-excited 3MLCT states of [Ru(bpy)3]2+ in [Zn(bpy)3](ClO4)2', Journal of Physical Chemistry, vol. 99, pp. 16807 - 16809

Riesen H; Wallace L; Krausz E, 1994, 'Localised 3MLCT states of [Ru(bpy)3-x(phen)x]2+ (x=0 to 3) in racemic [Zn(bpy)3] (ClO4)2', Chemical Physics Letters, vol. 228, pp. 605 - 609, http://dx.doi.org/10.1016/0009-2614(94)00983-X

Wallace L; Rillema DP, 1993, 'Photophysical Properties of Rhenium(I) Tricarbonyl Complexes Containing Alkyl- and Aryl-Substituted Phenanthrolines as Ligands', Inorganic Chemistry, vol. 32, pp. 3836 - 3843, http://dx.doi.org/10.1021/ic00070a012

Riesen H; Krausz E; Wallace L, 1992, 'Hole-burning and luminescence line narrowing in [IrCl2(5,6-Me2-phen)2]+. A strongly perturbed 3LC state', Journal of Physical Chemistry, vol. 96, pp. 3621 - 3626, http://dx.doi.org/10.1021/j100188a014

Wallace L; Heath GA; Krausz E; Moran G, 1991, 'Pathological Luminescence Characteristics of cis-[Ir(bpy)2Cl2]+', Inorganic Chemistry, vol. 30, pp. 347 - 349, http://dx.doi.org/10.1021/ic00002a040

Bochmann M; Creaser CS; Wallace L, 1990, 'Nickel catalysed cross-coupling reactions of grignard reagents with di-, tri- and polychlorobiphenyls', Journal of Molecular Catalysis, vol. 60, pp. 343 - 350, http://dx.doi.org/10.1016/0304-5102(90)85257-I

Conference Papers

Alrawashdeh L; Wallace L; Day AI, 2013, 'Strong Fluorescence Enhancement Of Cyclometalated Ir(III) Complexes In Cucurbit[10]uril', in Strong Fluorescence Enhancement Of Cyclometalated Ir(III) Complexes In Cucurbit[10]uril, 8th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC-8), ARLINGTON, VIRGINIA, USA, presented at 8th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC-8), ARLINGTON, VIRGINIA, USA, 07 July 2013 - 11 July 2013

Bali MS; Wallace L; Day AI; Armitt D, 2011, 'RAPID CHEMICAL NEUTRALISATION OF TATP', in RAPID CHEMICAL NEUTRALISATION OF TATP, PARARI 2011: 10th Australian Explosive Ordnance Symposium, Brisbane, Australia, presented at PARARI 2011: 10th Australian Explosive Ordnance Symposium, Brisbane, Australia, 08 November 2011 - 10 November 2011

Underwood C; Wall C; Day AI; Provatas A; Wallace L, 2009, 'Electrolytic treatment of nitroazole solutions in the synthesis of new high-nitrogen compounds', in Electrolytic treatment of nitroazole solutions in the synthesis of new high-nitrogen compounds, PARARI 2009: 9th Australian Explosives Ordnance Symposium, Adelaide, Australia, presented at PARARI 2009: 9th Australian Explosives Ordnance Symposium, Adelaide, Australia, 09 November 2009 - 11 November 2009

Underwood C; Day AI; Wallace L, 2008, 'Electrosynthetic Routes to New High-nitrogen Compounds Based on Triazoles and Triazolones', in Australian Energetic Materials Symposium: Abstracts, 1st Australian Energetic Materials Symposium, Flinders University, Adelaide, SA, presented at 1st Australian Energetic Materials Symposium, Flinders University, Adelaide, SA, 01 December 2008 - 02 December 2008

Randle K; Day AI; Wallace L; Kirkbride P; Lennard C, 2008, 'Detection of Peroxide-based Explosives', in Australian Energetic Materials Symposium: Abstracts, 1st Australian Energetic Materials Symposium, Flinders University, Adelaide, SA, presented at 1st Australian Energetic Materials Symposium, Flinders University, Adelaide, SA, 01 December 2008 - 02 December 2008

Wallace L; Underwood C; Cronin MP; Day AI; Larsson A; Willis A, 2007, 'Electrolytic treatment of NTO wastewaters and electrosynthesis of a new high-nitrogen compound', in PARARI 2007, Dept of Defence and Thales Australia, Australia, presented at PARARI 2007: 8th Australian Explosives Ordnance Symposium, Melbourne, Australia, 13 November 2007 - 15 November 2007

Conference Presentations

Bali MS; Wallace L; Armitt, D ; Day AI, 2013, 'TOWARDS THE CATALYTIC DEGRADATION OF PEROXIDE EXPLOSIVES', presented at 11th International Symposium on the Analysis and Detection of Explosives (ISADE), THE HAGUE, NETHERLANDS, 07 October 2013 - 10 October 2013

Alrawashdeh L; Wallace L; Day AI, 2013, 'Strong Fluorescence Enhancement Of Cyclometalated Ir(III) Complexes In Cucurbit[10]uril', presented at 8th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC-8), ARLINGTON, VIRGINIA, USA, 07 July 2013 - 11 July 2013

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